Email this article Complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with nickel nitrate in acetone
- Authors: Zhiltsova E.P.1, Lukashenko S.S.1, Ibatullina M.R.1,2, Kutyreva M.P.2, Zakharova L.Y.1
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Kazan Federal University
- Issue: Vol 90, No 7 (2016)
- Pages: 1374-1378
- Section: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/168446
- DOI: https://doi.org/10.1134/S0036024416070359
- ID: 168446
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Abstract
The complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with Ni(II) nitrate in acetone is studied by means of spectrophotometry (the Job–Ostromisslensky technique and molar ratios). The formation of 3: 1 and 1: 1 ligand: metal complexes is established and confirmed by mathematical modeling. The stability constants of the complexes and the change in the Gibbs free energy are determined.
About the authors
E. P. Zhiltsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Author for correspondence.
Email: Zhiltsova@iopc.ru
Russian Federation, Kazan, 420088
S. S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Russian Federation, Kazan, 420088
M. R. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University
Email: Zhiltsova@iopc.ru
Russian Federation, Kazan, 420088; Kazan, 420008
M. P. Kutyreva
Kazan Federal University
Email: Zhiltsova@iopc.ru
Russian Federation, Kazan, 420008
L. Ya. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Russian Federation, Kazan, 420088
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