电邮这篇文章 Complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with nickel nitrate in acetone
- 作者: Zhiltsova E.P.1, Lukashenko S.S.1, Ibatullina M.R.1,2, Kutyreva M.P.2, Zakharova L.Y.1
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隶属关系:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Kazan Federal University
- 期: 卷 90, 编号 7 (2016)
- 页面: 1374-1378
- 栏目: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/168446
- DOI: https://doi.org/10.1134/S0036024416070359
- ID: 168446
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详细
The complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with Ni(II) nitrate in acetone is studied by means of spectrophotometry (the Job–Ostromisslensky technique and molar ratios). The formation of 3: 1 and 1: 1 ligand: metal complexes is established and confirmed by mathematical modeling. The stability constants of the complexes and the change in the Gibbs free energy are determined.
作者简介
E. Zhiltsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
编辑信件的主要联系方式.
Email: Zhiltsova@iopc.ru
俄罗斯联邦, Kazan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, Kazan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University
Email: Zhiltsova@iopc.ru
俄罗斯联邦, Kazan, 420088; Kazan, 420008
M. Kutyreva
Kazan Federal University
Email: Zhiltsova@iopc.ru
俄罗斯联邦, Kazan, 420008
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
俄罗斯联邦, Kazan, 420088
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