Enviar artigo por via de e-mail Complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with nickel nitrate in acetone
- Autores: Zhiltsova E.P.1, Lukashenko S.S.1, Ibatullina M.R.1,2, Kutyreva M.P.2, Zakharova L.Y.1
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Afiliações:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Kazan Federal University
- Edição: Volume 90, Nº 7 (2016)
- Páginas: 1374-1378
- Seção: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/168446
- DOI: https://doi.org/10.1134/S0036024416070359
- ID: 168446
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Resumo
The complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with Ni(II) nitrate in acetone is studied by means of spectrophotometry (the Job–Ostromisslensky technique and molar ratios). The formation of 3: 1 and 1: 1 ligand: metal complexes is established and confirmed by mathematical modeling. The stability constants of the complexes and the change in the Gibbs free energy are determined.
Sobre autores
E. Zhiltsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Autor responsável pela correspondência
Email: Zhiltsova@iopc.ru
Rússia, Kazan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Rússia, Kazan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University
Email: Zhiltsova@iopc.ru
Rússia, Kazan, 420088; Kazan, 420008
M. Kutyreva
Kazan Federal University
Email: Zhiltsova@iopc.ru
Rússia, Kazan, 420008
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Rússia, Kazan, 420088
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