Мақаланы E-mail арқылы жіберу Complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with nickel nitrate in acetone
- Авторлар: Zhiltsova E.P.1, Lukashenko S.S.1, Ibatullina M.R.1,2, Kutyreva M.P.2, Zakharova L.Y.1
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Мекемелер:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Kazan Federal University
- Шығарылым: Том 90, № 7 (2016)
- Беттер: 1374-1378
- Бөлім: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/168446
- DOI: https://doi.org/10.1134/S0036024416070359
- ID: 168446
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Аннотация
The complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with Ni(II) nitrate in acetone is studied by means of spectrophotometry (the Job–Ostromisslensky technique and molar ratios). The formation of 3: 1 and 1: 1 ligand: metal complexes is established and confirmed by mathematical modeling. The stability constants of the complexes and the change in the Gibbs free energy are determined.
Авторлар туралы
E. Zhiltsova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Хат алмасуға жауапты Автор.
Email: Zhiltsova@iopc.ru
Ресей, Kazan, 420088
S. Lukashenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Ресей, Kazan, 420088
M. Ibatullina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan Federal University
Email: Zhiltsova@iopc.ru
Ресей, Kazan, 420088; Kazan, 420008
M. Kutyreva
Kazan Federal University
Email: Zhiltsova@iopc.ru
Ресей, Kazan, 420008
L. Zakharova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: Zhiltsova@iopc.ru
Ресей, Kazan, 420088
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