


Vol 126, No 6 (2025)
ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА
57Fe NMR and Mössbauer study of peculiarities of long-range magnetic ordering in Fe3C cementite
Abstract
The 57Fe NMR spectra and relaxation times in θ-Fe3C cementite in the region of long-range magnetic order were obtained and analyzed. The values of hyperfine magnetic fields for two nonequivalent positions of iron atoms in the structure (Pnma) of this compound and their evolution in the temperature range from 4.2 to 350 K were determined. From the analysis of the 57Fe Mossbauer spectra obtained at T = 295 K, the components of the electric field gradient tensor and the values of hyperfine fields were determined.



Dimensionality of exchange correlations of magnetization in high-entropy alloys FeCoNi(P)–W
Abstract
The high entropy (FeCoNiP)100-XWX coatings synthesized by chemical deposition have been investigated. Depending on the tungsten content, the coatings are a bcc solid solution or an amorphous alloy, or contain both phases simultaneously. From the analysis of the approach of magnetization to saturation by the correlation magnetometry method, it was found that the dimensionality of magnetization exchange correlations changes with a change in the tungsten concentration. At X > 10, three-dimensional exchange correlations of magnetization are realized, at 3 ≤Х ≤ 9 – two-dimensional exchange correlations, and at X < 3 – one-dimensional exchange correlations of magnetization. These observations can be attributed to the two-phase structure of the coating, along with the flattened shape of regions where the local easy magnetization axis remains uniform



THE CHANGE IN THE CRITICAL CURRENT OF SECOND-GENERATION HTS TAPES AFTER APPLIYING A COMPRESSIVE MECHANICAL LOADS
Abstract
Currently, projects of large-scale magnetic systems based on second-generation high-temperature superconductors (HTS) are actively being developed all over the world. Significant mechanical stresses occur during the production and operation of conductive elements, which can adversely affect the conductivity. In this study, an analysis was conducted on the changes in conductivity of HTS tapes with various architectures after applying compressive mechanical loads at room temperature. The HTS tapes produced at S-Innovations and those manufactured on the Kurchatov Institute's production line were used for investigation. It was shown that additional coating of HTS tape with POS-61 solder (Sn61/Pb39) lead to a decrease in conductivity at lower compressive mechanical loads compared to non-coated samples. It was also found that compressive loads of 50 MPa led to a significant increase in longitudinal inhomogeneity and local increase in critical current above values in original tape. Comparative analysis of critical currents obtained using transport method and calculated from Hall magnetometry data was carried out. Results obtained by these complementary methods were consistent for all samples if exponential form of local volt-ampere characteristic was assumed.



The Height of the Potential Barrier of the Yang–Teller Center in Spinel ZnGa2O4
Abstract
The EPR spectrum of the copper Cu2+ impurity magnetic center in a single crystal of zinc-gallium spinel ZnGa2O4 has been studied in a wide temperature range T = 4.2–300 K. The EPR spectrum exhibits properties similar to those for off-center ions, which contribute to the formation of a multiminimum crystal field potential in the immediate environment of the Yang–Teller Cu2+ copper complex in a single crystal. A study of the temperature dependence of the integral intensity of the EPR spectrum lines has been carried out. The height of the potential barrier that separates the equivalent potential pits containing Cu2+ copper ions has been determined. Cu2+ ions occupy structurally unequal centers in the elementary crystal lattice.



Modeling of three-state antiferromagnetic potts model on a simple cubic lattice by the monte carlo method
Abstract
Computer simulation of phase transitions in a three-state antiferromagnetic Potts model on a simple cubic lattice is carried out. Using the Monte Carlo method, the temperature dependences of the order parameter mAF, the susceptibility χ, and the heat capacity C. Systems with linear dimensions L×L×L=N, L=10–50 are considered. Using histogram data analysis and the fourth-order Binder cumulant method it is shown that a second-order phase transition occurs in the Potts model under consideration. The critical temperature Tc has been determined with good accuracy.



MAGNETIC PROPERTIES OF (NI–CO)@C NANOCOMPOSITES: EFFECT OF CARBON
Abstract
Nanocomposites (Ni–Co)@C with different Ni:Co ratios and core-shell structure were obtained by gas-phase synthesis. Structural and phase analysis of the samples was carried out using X-ray diffraction and transmission electron microscopy. The size of the metal core of particles, determined from X-ray data, is (7–8) nm, the shell thickness, several nm. Magnetic properties and 59Co NMR spectra were measured before and after annealing at different temperatures. The evolution of properties and NMR spectra with varying cobalt content and as a result of heat treatments is interpreted in the context of changes in the carbon content in the core of composites.



СТРУКТУРА, ФАЗОВЫЕ ПРЕВРАЩЕНИЯ И ДИФФУЗИЯ
Structural changes and mechanism of convergence of cylindrical shells made of stainless austenitic steel 12X18N10T under explosive loading
Abstract
Experiments were performed on the convergence of cylindrical shells made of austenitic steel 12H18N10T under the action of an explosion. The initiation of the explosive layer surrounding the shell was carried out from eight points evenly distributed on the cylindrical surface. It was established that the convergence process consists of the division of the shells into similar fragments and their movement toward the shell axis. The study of the microstructure showed that shear bands are formed, which create teeth when they reach the surface. Comparison of the processes of convergence of steel shells and previously studied copper ones showed that there are two different mechanisms of convergence: solid-state and hydrodynamic. The deformation criterion for the onset of instability was determined and the size of the instability region was estimated



Microstructure and properties of metastable (Α+Β) shape memory alloy Cu–41 wt%Zn subjected to cryothermal and mechanocycling
Abstract
Structural and phase transformations and properties of (a+b) Cu–41 wt%Zn shape memory alloy were studied depending on cryothermal and mechanocycling modes. The temperatures of the start and finish of the direct and reverse martensitic transformations are determined by the temperature dependences of electrical resistance. The mechanical properties were measured in mechanocyclic tensile tests in austenitic and martensitic states. Methods of optical, scanning and transmission electron microscopy and X-ray phase analysis were used in structural studies. An increase in the critical temperatures of the start of direct and reverse thermoelastic martensitic transformations (by no more than 25°) with an increase in the number of thermal cycles “cooling–heating” was revealed. An increase in tweed contrast on electron microscopic images and diffuse effects on electron diffraction patterns on B2-austenite is shown with an increase in the number of cryothermocycles. An increase in dislocation density due to phase locking during thermal cycling was found. The low-temperature effect of ferroelasticity in the alloy has been established.



Effect of composition and annealing temperature on the structure and properties of Cu–Ni alloys processed by severe plastic deformation
Abstract
The structure of Cu–Ni alloys processed by high-pressure torsion (HPT) by 5 revolutions at room temperature and its thermal stability under subsequent annealing have been studied using transmission electron microscopy and microhardness measurements. The influence of three main factors on the structure and microhardness under deformation and annealing depending on the composition has been revealed: the changes in homologous temperature and stacking fault energies (SFE) and the effect of solid solution formation. The combination of these factors results in the non-monotonic change in the structure obtained by HPT (crystallite sizes and microhardness) and its thermal stability depending on the alloy composition. In copper-rich alloys, a decrease in the homologous temperature with an increase in Ni content plays a decisive role in the refinement of the structure, strengthening and thermal stability. When Ni is alloyed with Cu, the structure and its thermal stability do not change as significantly, since the increase in homologous temperature and the decrease in SFE compensate each other, but due to the effect of solid solution formation in alloys with a nearly equiatomic composition, the most dispersed and thermally stable structure is formed.



Darken’s Equations for Determination of Partial Diffusion Coefficients in Multicomponent Systems
Abstract
The problem of determination of partial diffusion coefficients in multicomponent systems was solved in this study. Using the Darken’s hypothesis, for each component the equation for the relationship between the partial diffusion coefficients of the components Di and the interdiffusion coefficient Di determined from the concentration curve of each component in multicomponent diffusion pair was obtained. The obtained Darken’s equations coincide in form with the Onsager’s equations for multicomponent systems. It follows that for multicomponent systems n2 diffusion coefficients according to Onsager are functions of n partial diffusion coefficients of the components according to Darken. The operability of the obtained equations and methods for calculating the parameters is tested on a virtual three-component system A+B+C. The calculated values of the partial coefficients reproduce with high accuracy the initial values used to simulate the diffusion process. The technique is applied to a real Co–Mo–W system. For the first time, the partial diffusion coefficients of cobalt, molybdenum and tungsten are determined at 1373 K in the cobalt corner of the Co–Mo–W system. Partial coefficients are used to predict the interaction between cobalt alloys doped with molybdenum and tungsten. The results of the prediction are in satisfactory agreement with the experiment.



Periodic carbon structures on the surface of metallic nickel
Abstract
Using the example of metallic nickel, the possibility of synthesizing periodic carbon structures by chemical vapor deposition (CVD) without applying an additional catalyst to the surface of metals that are catalytically active in hydrocarbon pyrolysis processes has been experimentally demonstrated. Planar and non-planar structures of sub-millimeter (~500×500 μm2) scale have been obtained on polycrystalline nickel substrates. The surface structuring of nickel substrates was performed by local modification of the surface catalytic properties, as well as by forming the surface relief by the method of plastic surface deformation using a template. For planar structures, the modification of the surface properties was carried out by ion bombardment through a mask. For non-planar structures, the local activation of the passivated surface was carried out by mechanical grinding-polishing. The obtained structures contain two forms of carbon: turbo-substrate graphite and carbon nanotubes. It has been established that both forms of carbon can be produced in a single CVD process.



ПРОЧНОСТЬ И ПЛАСТИЧНОСТЬ
Model of Void Formation on Wedge Disclination
Abstract
A model of voids formation during plastic deformation is proposed, based on the concept of crack formation in the field of elastic stresses of a negative disclination and its subsequent blunting due to accommodative plastic deformation. A detailed analysis of the main characteristics of a disclination crack is carried out. Analytical expressions are obtained for the stress intensity factors at its tips, the distribution of the Burgers vector density and the profile of its opening depending on the material parameters and disclination characteristics. The stability conditions of a symmetric microcrack with a disclination located in its center are investigated. For this configuration of defects, the dependence of the value of plastic crack opening on the disclination strength, the elastic field screening radius and the mechanical constants of the material is obtained.


