High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with  N -Phenylmaleimide

D. A. Kornilov; V. D. Kiselev; O. V. Anikin; A. O. Kolesnikova; A. A. Shulyat’ev

doi:10.1134/S1070428019010020

High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with N-Phenylmaleimide

Авторы: Kornilov D.A.¹, Kiselev V.D.¹, Anikin O.V.¹, Kolesnikova A.O.¹, Shulyat’ev A.A.¹
Учреждения:
1. Butlerov Institute of Chemistry
Выпуск: Том 55, № 1 (2019)
Страницы: 7-10
Раздел: Article
URL: https://bakhtiniada.ru/1070-4280/article/view/219683
DOI: https://doi.org/10.1134/S1070428019010020
ID: 219683

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Аннотация

The effects of temperature, solvent nature, and high pressure on the rate of the Diels-Alder reaction of furan with N-phenylmaleimide were studied. A weak acceleration of the title reaction in proton-donor media was observed in comparison to other cycloaddition and ene reactions. The volumes of activation and reaction coincided within the experimental error, in keeping with the presumed cyclic transition state.