High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with  N -Phenylmaleimide

D. A. Kornilov; V. D. Kiselev; O. V. Anikin; A. O. Kolesnikova; A. A. Shulyat’ev

doi:10.1134/S1070428019010020

High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with N-Phenylmaleimide

Authors: Kornilov D.A.¹, Kiselev V.D.¹, Anikin O.V.¹, Kolesnikova A.O.¹, Shulyat’ev A.A.¹
Affiliations:
1. Butlerov Institute of Chemistry
Issue: Vol 55, No 1 (2019)
Pages: 7-10
Section: Article
URL: https://bakhtiniada.ru/1070-4280/article/view/219683
DOI: https://doi.org/10.1134/S1070428019010020
ID: 219683

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The effects of temperature, solvent nature, and high pressure on the rate of the Diels-Alder reaction of furan with N-phenylmaleimide were studied. A weak acceleration of the title reaction in proton-donor media was observed in comparison to other cycloaddition and ene reactions. The volumes of activation and reaction coincided within the experimental error, in keeping with the presumed cyclic transition state.