High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with N-Phenylmaleimide


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The effects of temperature, solvent nature, and high pressure on the rate of the Diels-Alder reaction of furan with N-phenylmaleimide were studied. A weak acceleration of the title reaction in proton-donor media was observed in comparison to other cycloaddition and ene reactions. The volumes of activation and reaction coincided within the experimental error, in keeping with the presumed cyclic transition state.

Sobre autores

D. Kornilov

Butlerov Institute of Chemistry

Email: vkiselev.ksu@gmail.com
Rússia, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

V. Kiselev

Butlerov Institute of Chemistry

Autor responsável pela correspondência
Email: vkiselev.ksu@gmail.com
Rússia, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

O. Anikin

Butlerov Institute of Chemistry

Email: vkiselev.ksu@gmail.com
Rússia, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

A. Kolesnikova

Butlerov Institute of Chemistry

Email: vkiselev.ksu@gmail.com
Rússia, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

A. Shulyat’ev

Butlerov Institute of Chemistry

Email: vkiselev.ksu@gmail.com
Rússia, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

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