Email this article Chemical Transformations of Tetracyclo[3.3.1.1.3,7.0.1,3]decane (1,3-Dehydroadamantane): VIII. Reaction of 1,3-Dehydroadamantane with Aliphatic Aldehydes
- Authors: Mokhov V.M.1, Saad K.R.2, Parshin G.Y.1, Butov G.M.1,2
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Affiliations:
- Volgograd State Technical University
- Volzhsky Polytechnic Institute (Branch)
- Issue: Vol 55, No 5 (2019)
- Pages: 640-645
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/220531
- DOI: https://doi.org/10.1134/S1070428019050099
- ID: 220531
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Abstract
The reaction of 1,3-dehydroadamantane with aliphatic aldehydes involves the Ca-H bond and forms hardly accessible branched 2-(1-adamantyl)alkylaldehydes in one stage in a yield of 60-78%. It is found that 2-(1-adamantyl)alkylaldehydes are prone to oligomerization. The reaction of 2-(1-adamantyl)-alkylaldehydes with 2,4-dinitrophenylhydrazine gave the corresponding hydrazones in a yield of 84-98%.
About the authors
V. M. Mokhov
Volgograd State Technical University
Author for correspondence.
Email: tons@vstu.ru
Russian Federation, pr. Lenina 28b, Volgograd, 400131
K. R. Saad
Volzhsky Polytechnic Institute (Branch)
Email: butov@post.volpi.ru
Russian Federation, ul. Engelsa 42, Volzhskii, Volgograd obl., 404121
G. Yu. Parshin
Volgograd State Technical University
Email: butov@post.volpi.ru
Russian Federation, pr. Lenina 28b, Volgograd, 400131
G. M. Butov
Volgograd State Technical University; Volzhsky Polytechnic Institute (Branch)
Author for correspondence.
Email: butov@post.volpi.ru
Russian Federation, pr. Lenina 28b, Volgograd, 400131; ul. Engelsa 42, Volzhskii, Volgograd obl., 404121
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