Investigation of the Diastomerism of Compounds with a Long-Chain Tether between the Stereogenic Centers
- Authors: Talsi V.P.1, Evdokimov S.N.1, Shatsauskas A.L.2
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Affiliations:
- Institute of Hydrocarbon Processing Problems, Siberian Branch
- Omsk State Technical University
- Issue: Vol 55, No 2 (2019)
- Pages: 161-167
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/219808
- DOI: https://doi.org/10.1134/S1070428019020064
- ID: 219808
Cite item
Abstract
The NMR spectra of several heterocyclic compounds synthesized at Omsk universities revealed manifestation of a diasteomerism at a large (up to fifteen bonds) distance between the stereogenic centers. This phenomenon was explained by a regular helical secondary structure of the tether between the centers.
About the authors
V. P. Talsi
Institute of Hydrocarbon Processing Problems, Siberian Branch
Author for correspondence.
Email: vtalsi@ihcp.ru
Russian Federation, ul. Neftezavodskaya 54, Omsk, 644040
S. N. Evdokimov
Institute of Hydrocarbon Processing Problems, Siberian Branch
Email: vtalsi@ihcp.ru
Russian Federation, ul. Neftezavodskaya 54, Omsk, 644040
A. L. Shatsauskas
Omsk State Technical University
Email: vtalsi@ihcp.ru
Russian Federation, pr. Mira 11, Omsk, 644050
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