Email this article New chiral block for cyclopentanoids synthesis
- Authors: Gimazetdinov A.M.1, Almukhametov V.Z.1, Loza V.V.1, Miftakhov M.S.1
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Affiliations:
- Ufa Institute of Chemistry
- Issue: Vol 52, No 5 (2016)
- Pages: 670-675
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/214292
- DOI: https://doi.org/10.1134/S1070428016050092
- ID: 214292
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Abstract
Hydroxymethylation of bicyclic allylsilane, (3aR,6R,6aS)-3,3a,6,6a-tetrahydro-6-(trimethylsilyl)-cyclopenta[c]furan-1-one with formaldehyde by Prins reaction proceeds via SE2' mechanism with the formation of anti-addition product. Some reactions of obtained (3aS,4S,6aR)-4-(hydroxymethyl)-3,3a,4,6a-tetrahydro-1H-cyclopenta[c]furan-1-one were investigated.
About the authors
A. M. Gimazetdinov
Ufa Institute of Chemistry
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054
V. Z. Almukhametov
Ufa Institute of Chemistry
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054
V. V. Loza
Ufa Institute of Chemistry
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054
M. S. Miftakhov
Ufa Institute of Chemistry
Author for correspondence.
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054
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