New chiral block for cyclopentanoids synthesis

A. M. Gimazetdinov; V. Z. Almukhametov; V. V. Loza; M. S. Miftakhov

doi:10.1134/S1070428016050092

New chiral block for cyclopentanoids synthesis

作者: Gimazetdinov A.M.¹, Almukhametov V.Z.¹, Loza V.V.¹, Miftakhov M.S.¹
隶属关系:
1. Ufa Institute of Chemistry
期: 卷 52, 编号 5 (2016)
页面: 670-675
栏目: Article
URL: https://bakhtiniada.ru/1070-4280/article/view/214292
DOI: https://doi.org/10.1134/S1070428016050092
ID: 214292

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Hydroxymethylation of bicyclic allylsilane, (3aR,6R,6aS)-3,3a,6,6a-tetrahydro-6-(trimethylsilyl)-cyclopenta[c]furan-1-one with formaldehyde by Prins reaction proceeds via S_E2' mechanism with the formation of anti-addition product. Some reactions of obtained (3aS,4S,6aR)-4-(hydroxymethyl)-3,3a,4,6a-tetrahydro-1H-cyclopenta[c]furan-1-one were investigated.