Kinetics and mechanism of the catalytic reaction between alcohols and dimethyl carbonate

K. F. Koledina; S. N. Koledin; N. A. Shchadneva; I. M. Gubaidullin

doi:10.1134/S003602441703013X

Kinetics and mechanism of the catalytic reaction between alcohols and dimethyl carbonate

作者: Koledina K.F.¹^,2, Koledin S.N.¹^,2, Shchadneva N.A.¹, Gubaidullin I.M.¹^,2
隶属关系:
1. Institute of Petrochemistry and Catalysis
2. Ufa State Oil Technical University
期: 卷 91, 编号 3 (2017)
页面: 442-447
栏目: Chemical Kinetics and Catalysis
URL: https://bakhtiniada.ru/0036-0244/article/view/169304
DOI: https://doi.org/10.1134/S003602441703013X
ID: 169304

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详细

The mechanism of the reaction between alcohols and dimethyl carbonate, catalyzed by dicobalt octacarbonyl Co₂(CO)₈, is studied by means of mathematical modeling. Kinetic models for possible schemes of chemical transformations are constructed at different initial concentrations of the catalyst. Based on a comparative analysis of activation energies of possible stages of chemical transformations, possible reaction pathways are determined and an appropriate mechanism is selected.