Отправить статью по E-mail Kinetics and mechanism of the catalytic reaction between alcohols and dimethyl carbonate
- Авторы: Koledina K.F.1,2, Koledin S.N.1,2, Shchadneva N.A.1, Gubaidullin I.M.1,2
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Учреждения:
- Institute of Petrochemistry and Catalysis
- Ufa State Oil Technical University
- Выпуск: Том 91, № 3 (2017)
- Страницы: 442-447
- Раздел: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/169304
- DOI: https://doi.org/10.1134/S003602441703013X
- ID: 169304
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Аннотация
The mechanism of the reaction between alcohols and dimethyl carbonate, catalyzed by dicobalt octacarbonyl Co2(CO)8, is studied by means of mathematical modeling. Kinetic models for possible schemes of chemical transformations are constructed at different initial concentrations of the catalyst. Based on a comparative analysis of activation energies of possible stages of chemical transformations, possible reaction pathways are determined and an appropriate mechanism is selected.
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K. Koledina
Institute of Petrochemistry and Catalysis; Ufa State Oil Technical University
Автор, ответственный за переписку.
Email: koledinakamila@mail.ru
Россия, Ufa, 450077; Ufa, 450000
S. Koledin
Institute of Petrochemistry and Catalysis; Ufa State Oil Technical University
Email: koledinakamila@mail.ru
Россия, Ufa, 450077; Ufa, 450000
N. Shchadneva
Institute of Petrochemistry and Catalysis
Email: koledinakamila@mail.ru
Россия, Ufa, 450077
I. Gubaidullin
Institute of Petrochemistry and Catalysis; Ufa State Oil Technical University
Email: koledinakamila@mail.ru
Россия, Ufa, 450077; Ufa, 450000
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