Changes in the Crystal Lattice Parameters of Montmorillonite during Its Modification by Cobalt and Aluminum Cations


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The effect the modification (pillarization) of montmorillonite clays from different locations has on the crystallographic lattice parameters of montmorillonite is determined. It is revealed through ultrahigh resolution transmission electron microscopy and analyzing microdiffraction patterns that pillarization raises the distance between montmorillonite structural units to 2.2 nm, while the intracrystal distance between the atoms grows by 0.4 nm. The catalytic activity of specimens in the oxidation reaction between organic dyes and hydrogen peroxide is enhanced 2–3 times.

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P. Sokolovskiy

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

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俄罗斯联邦, Moscow, 119991

F. Roessner

Ossietzky University of Oldenburg

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Email: frank.roessner@uni-oldenburg.de
德国, Oldenburg, 26129

A. Vezentsev

Belgorod National State Research University

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Email: vesentsev@bsu.edu.ru
俄罗斯联邦, Belgorod, 308015

T. Konkova

Mendeleev University of Chemical Technology of Russia

Email: manohin@bk.ru
俄罗斯联邦, Moscow, 125047

M. Alekhina

Mendeleev University of Chemical Technology of Russia

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Email: mbalekhina@yandex.ru
俄罗斯联邦, Moscow, 125047

S. Manokhin

Institute of Problems of Chemical Physics of the Russian Academy of Sciences

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Email: manohin@bk.ru
俄罗斯联邦, Moscow, 142432

A. Greish

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: manohin@bk.ru
俄罗斯联邦, Moscow, 119991

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