Email this article Changes in the Crystal Lattice Parameters of Montmorillonite during Its Modification by Cobalt and Aluminum Cations
- Authors: Sokolovskiy P.V.1, Roessner F.2, Vezentsev A.I.3, Konkova T.V.4, Alekhina M.B.4, Manokhin S.S.5, Greish A.A.1
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Affiliations:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Ossietzky University of Oldenburg
- Belgorod National State Research University
- Mendeleev University of Chemical Technology of Russia
- Institute of Problems of Chemical Physics of the Russian Academy of Sciences
- Issue: Vol 92, No 10 (2018)
- Pages: 1947-1952
- Section: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/170160
- DOI: https://doi.org/10.1134/S0036024418100333
- ID: 170160
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Abstract
The effect the modification (pillarization) of montmorillonite clays from different locations has on the crystallographic lattice parameters of montmorillonite is determined. It is revealed through ultrahigh resolution transmission electron microscopy and analyzing microdiffraction patterns that pillarization raises the distance between montmorillonite structural units to 2.2 nm, while the intracrystal distance between the atoms grows by 0.4 nm. The catalytic activity of specimens in the oxidation reaction between organic dyes and hydrogen peroxide is enhanced 2–3 times.
About the authors
P. V. Sokolovskiy
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: carbsorb@gmail.com
Russian Federation, Moscow, 119991
F. Roessner
Ossietzky University of Oldenburg
Author for correspondence.
Email: frank.roessner@uni-oldenburg.de
Germany, Oldenburg, 26129
A. I. Vezentsev
Belgorod National State Research University
Author for correspondence.
Email: vesentsev@bsu.edu.ru
Russian Federation, Belgorod, 308015
T. V. Konkova
Mendeleev University of Chemical Technology of Russia
Email: manohin@bk.ru
Russian Federation, Moscow, 125047
M. B. Alekhina
Mendeleev University of Chemical Technology of Russia
Author for correspondence.
Email: mbalekhina@yandex.ru
Russian Federation, Moscow, 125047
S. S. Manokhin
Institute of Problems of Chemical Physics of the Russian Academy of Sciences
Author for correspondence.
Email: manohin@bk.ru
Russian Federation, Moscow, 142432
A. A. Greish
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: manohin@bk.ru
Russian Federation, Moscow, 119991
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