Standard thermodynamic functions and constants of the formation of Nd3+ and Lа3+ complexes with glycine in aqueous solutions at 298 K


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Abstract

The enthalpies of complexation of glycine (HGly±) with Nd3+ and La3+ ions at 298.15 K and at an ionic strength of 0.5 (KNO3) are determined by means of calorimetry. The thermodynamic characteristics of the reactions of formation are calculated for NdGly2+, NdGly2+, LaGly2+, and LaGly2+ complexes.

About the authors

N. V. Chernyavskaya

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: natchernyavskaya@mail.ru
Russian Federation, Ivanovo, 153460

A. I. Lytkin

Ivanovo State University of Chemistry and Technology

Email: natchernyavskaya@mail.ru
Russian Federation, Ivanovo, 153460

A. S. Chernov

Ivanovo State University of Chemistry and Technology

Email: natchernyavskaya@mail.ru
Russian Federation, Ivanovo, 153460

V. E. Litvinenko

Kostroma State University

Email: natchernyavskaya@mail.ru
Russian Federation, Kostroma, 156005

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