Ozone production and losses in N2/O2 mixtures in an ozone generator
- Authors: Mankelevich Y.A.1, Poroykov A.Y.1, Rakhimova T.V.1, Voloshin D.G.1, Chukalovskii A.A.1, Zosimov A.V.2, Lunin V.V.2, Samoilovich V.G.2
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Affiliations:
- Skobel’tsyn Institute of Nuclear Physics
- Department of Chemistry
- Issue: Vol 90, No 9 (2016)
- Pages: 1896-1902
- Section: Colloid Chemistry and Electrochemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/168789
- DOI: https://doi.org/10.1134/S0036024416090181
- ID: 168789
Cite item
Abstract
Nonunique ozone concentrations at the output of an ozone generator under identical external conditions of barrier discharge activation of N2/O2 mixtures but with different prehistories of operating practice and employed gas mixtures are investigated theoretically. An analytical approach is developed to determine the ozone yield with regard for its heterogeneous loss. Plasma-chemical and electron kinetics in the N2/O2-mixtures are calculated numerically. The results of numerical calculations are compared to experimental data obtained by the authors. It is noted that the heterogeneous loss of ozone is the probable reason for the observed variety of behavior of О3 concentrations, depending on prehistory of ozone generator operation, along with the N2 and O2 gas flow rates and the specific active power.
About the authors
Yu. A. Mankelevich
Skobel’tsyn Institute of Nuclear Physics
Author for correspondence.
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119899
A. Yu. Poroykov
Skobel’tsyn Institute of Nuclear Physics
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119899
T. V. Rakhimova
Skobel’tsyn Institute of Nuclear Physics
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119899
D. G. Voloshin
Skobel’tsyn Institute of Nuclear Physics
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119899
A. A. Chukalovskii
Skobel’tsyn Institute of Nuclear Physics
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119899
A. V. Zosimov
Department of Chemistry
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119991
V. V. Lunin
Department of Chemistry
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119991
V. G. Samoilovich
Department of Chemistry
Email: ymankelevich@mics.msu.su
Russian Federation, Moscow, 119991
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