Structure of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands


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The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.

作者简介

V. Sergienko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: sergienko@igic.ras.ru
俄罗斯联邦, Moscow, 119991; Moscow, 125190

S. Strashnova

Peoples’ Friendship University of Russia

Email: sergienko@igic.ras.ru
俄罗斯联邦, Moscow, 117198

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