Email this article Structure of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands
- Authors: Sergienko V.S.1,2, Strashnova S.B.3
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences
- Peoples’ Friendship University of Russia
- Issue: Vol 64, No 7 (2019)
- Pages: 882-885
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/169414
- DOI: https://doi.org/10.1134/S0036023619070143
- ID: 169414
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Abstract
The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125190
S. B. Strashnova
Peoples’ Friendship University of Russia
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 117198
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