Structure of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands


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The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.

Sobre autores

V. Sergienko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences

Autor responsável pela correspondência
Email: sergienko@igic.ras.ru
Rússia, Moscow, 119991; Moscow, 125190

S. Strashnova

Peoples’ Friendship University of Russia

Email: sergienko@igic.ras.ru
Rússia, Moscow, 117198

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