Influence of the composition of [Ti(OC4H9)4 – x(O2C5H7)x] complexes and hydrolysis conditions on the synthesis of titania by sol–gel technology


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The influence of the coordination sphere of [Ti(OC4H9)4–x(O2C5H7)x] complexes, concentration in solution, and the ratio n(H2O)/n(Ti4+) on the hydrolysis and polycondensation kinetics of the complexes, the stability of the resulting gels, the thermal behavior of then-formed xerogels, the shift of anatase–rutile phase transition temperature, and the microstructure of the product, was determined.

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N. Simonenko

Kurnakov Institute of General and Inorganic Chemistry

编辑信件的主要联系方式.
Email: n_simonenko@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

V. Nikolaev

Kurnakov Institute of General and Inorganic Chemistry

Email: n_simonenko@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

E. Simonenko

Kurnakov Institute of General and Inorganic Chemistry; Samara State Aerospace University (National Research University)

Email: n_simonenko@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; Samara

V. Sevastyanov

Kurnakov Institute of General and Inorganic Chemistry; Samara State Aerospace University (National Research University)

Email: n_simonenko@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; Samara

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry; Samara State Aerospace University (National Research University)

Email: n_simonenko@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; Samara

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