Influence of the composition of [Ti(OC4H9)4 – x(O2C5H7)x] complexes and hydrolysis conditions on the synthesis of titania by sol–gel technology
- Авторы: Simonenko N.P.1, Nikolaev V.A.1, Simonenko E.P.1,2, Sevastyanov V.G.1,2, Kuznetsov N.T.1,2
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Samara State Aerospace University (National Research University)
- Выпуск: Том 61, № 8 (2016)
- Страницы: 929-939
- Раздел: Synthesis and Properties of Inorganic Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/166659
- DOI: https://doi.org/10.1134/S0036023616080167
- ID: 166659
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Аннотация
The influence of the coordination sphere of [Ti(OC4H9)4–x(O2C5H7)x] complexes, concentration in solution, and the ratio n(H2O)/n(Ti4+) on the hydrolysis and polycondensation kinetics of the complexes, the stability of the resulting gels, the thermal behavior of then-formed xerogels, the shift of anatase–rutile phase transition temperature, and the microstructure of the product, was determined.
Об авторах
N. Simonenko
Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: n_simonenko@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991
V. Nikolaev
Kurnakov Institute of General and Inorganic Chemistry
Email: n_simonenko@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991
E. Simonenko
Kurnakov Institute of General and Inorganic Chemistry; Samara State Aerospace University (National Research University)
Email: n_simonenko@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991; Samara
V. Sevastyanov
Kurnakov Institute of General and Inorganic Chemistry; Samara State Aerospace University (National Research University)
Email: n_simonenko@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991; Samara
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry; Samara State Aerospace University (National Research University)
Email: n_simonenko@mail.ru
Россия, Leninskii pr. 31, Moscow, 119991; Samara
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