Crystal Structures of Two Luminescent Mononuclear and dinuclear cyclopalladated 2-(4-Ethylphenyl)pyrazine complexes


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Two mononuclear and dinuclear cyclopalladated 2-(4-ethylphenyl)pyrazine (epp) complexes 2 and 3 are prepared in the bridge-splitting reactions of palladacyclic dimer 1 with PPh3 (2) and 1,4- bis(diphenylphosphino)butane (dppb) (3). Their crystal and molecular structures are determined by the single crystal X-ray analysis. C–H⋯N(Cl) hydrogen bonds and π⋯π interactions are found in the the crystals.

Sobre autores

H. Li

College of Chemistry and Chemical Engineering

Email: xubohan@163.com
República Popular da China, Luoyang, Henan

Z. Wang

College of Chemistry and Chemical Engineering

Email: xubohan@163.com
República Popular da China, Luoyang, Henan

W. Fu

College of Chemistry and Chemical Engineering

Email: xubohan@163.com
República Popular da China, Luoyang, Henan

C. Xu

College of Chemistry and Chemical Engineering; College of Food and Pharmacy

Autor responsável pela correspondência
Email: xubohan@163.com
República Popular da China, Luoyang, Henan; Luoyang, Henan

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