Email this article Crystal Structures of Two Luminescent Mononuclear and dinuclear cyclopalladated 2-(4-Ethylphenyl)pyrazine complexes
- Authors: Li H.M.1, Wang Z.Q.1, Fu W.J.1, Xu C.1,2
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Affiliations:
- College of Chemistry and Chemical Engineering
- College of Food and Pharmacy
- Issue: Vol 59, No 1 (2018)
- Pages: 209-213
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161859
- DOI: https://doi.org/10.1134/S002247661801033X
- ID: 161859
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Abstract
Two mononuclear and dinuclear cyclopalladated 2-(4-ethylphenyl)pyrazine (epp) complexes 2 and 3 are prepared in the bridge-splitting reactions of palladacyclic dimer 1 with PPh3 (2) and 1,4- bis(diphenylphosphino)butane (dppb) (3). Their crystal and molecular structures are determined by the single crystal X-ray analysis. C–H⋯N(Cl) hydrogen bonds and π⋯π interactions are found in the the crystals.
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About the authors
H. M. Li
College of Chemistry and Chemical Engineering
Email: xubohan@163.com
China, Luoyang, Henan
Z. Q. Wang
College of Chemistry and Chemical Engineering
Email: xubohan@163.com
China, Luoyang, Henan
W. J. Fu
College of Chemistry and Chemical Engineering
Email: xubohan@163.com
China, Luoyang, Henan
C. Xu
College of Chemistry and Chemical Engineering; College of Food and Pharmacy
Author for correspondence.
Email: xubohan@163.com
China, Luoyang, Henan; Luoyang, Henan
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