Vol 26, No 2 (2022)
Mechanical Engineering
Influence of the main parameters of a dual-mass oscillation system on its dynamic characteristics
Abstract
164-172
Numerical analysis of dynamics and durability of rotor elements in gas turbine engines
Abstract
173-183
Technological support of digital production when processing parts using a ball-rod hardener
Abstract
184-196
Power Engineering
Development of an artificial neural network-based method for determining the flexibility of power systems with high share of wind generation
Abstract
197-216
Increasing the efficiency of wind farms
Abstract
217-227
Flicker elimination in grids with distributed generation using group predictive voltage and frequency regulators
Abstract
228-244
Reliability methods for delivery of primary energy resources at a power plant during a reliability audit of electric energy systems
Abstract
245-259
Determination of heat-transfer coefficients in multi-vortex heat-mass-exchange apparatus
Abstract
260-269
Thermogravimetric analysis of the combustion of Tuva coals before and after their carbonization
Abstract
270-283
Study of operational modes of an "electric drive–turbomachinery–pipeline" technological complex
Abstract
284-296
Justification of the need to improve emergency control systems for preventing disturbances of voltage stability in power systems
Abstract
297-309
Power control of electric heating elements using thyristor voltage and resistance converters
Abstract
310-319
Metallurgy
The feasibility of hydrometallurgical methods for enhancing the processing of copper concentrates
Abstract
320-335
Phase equilibria in Hg-Al system during vacuum distillation
Abstract
336-347
Physicochemical parameters of a hydrochemical technology employing sodium chloride to obtain cryolite used in aluminium production
Abstract
The paper aims to study the physicochemical parameters of a hydrochemical technology employing hydrofluoric acid and local mineral resources (sodium chloride) to obtain cryolite used in the electrolysis of cryolite-alumina melts. In order to determine the elemental chemical and phase compositions of initial, intermediate, and final products, titration and X-ray diffraction analysis (using an upgraded Dron-2 unit) were employed. The conducted studies indicate that the proposed process of cryolite production from hydrofluoric acid at 28–30 % concentration using aluminium hydroxide and a concentrated sodium chloride solution occurs at 25 °С for 10–15 min. The yield of cryolite reaches 87.6 %, while ~12 % of cryolite remains dissolved in the hydrochloric acid solution. With the temperature rising from 25°С to 95°С, the cryolite yield is shown to decrease from 87.6 % to 69.3 % due to its higher solubility in the formed hydrochloric acid. The cryolite production process was validated via X-ray diffraction analysis. The analysed sample was found to be consistent with the cryolite reference, i. e., indicating an interaction between sodium chloride and fluoroaluminic acid. The conducted studies served as a basis for developing a process flow diagram of hydrochemical cryolite production using hydrofluoric acid, aluminium hydroxide, and sodium chloride. The conducted studies revealed that the technology of cryolite production employing sodium chloride is easy to implement and cost-effective due to the use of local mineral resources and low energy consumption.
348-356





