Reaction of 2-chloromethylphenols with enaminones

A. V. Lukashenko; D. V. Osipov; V. A. Osyanin; Yu. N. Klimochkin

doi:10.1134/S1070428016120186

Reaction of 2-chloromethylphenols with enaminones

作者: Lukashenko A.V.¹, Osipov D.V.¹, Osyanin V.A.¹, Klimochkin Y.N.¹
隶属关系:
1. Samara State Technical University
期: 卷 52, 编号 12 (2016)
页面: 1817-1821
栏目: Article
URL: https://bakhtiniada.ru/1070-4280/article/view/215488
DOI: https://doi.org/10.1134/S1070428016120186
ID: 215488

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The reaction of o-(chloromethyl)phenols with enamino ketones afforded a series of 3-acyl- and 3-formyl-4H-chromenes as a result of cascade transformation including [4 + 2]-cycloaddition of enamino ketone to o-quinone methide generated in situ and subsequent elimination of secondary amine.