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Reaction of N-sulfonyl derivatives of 1,4-benzoquinone monoimine with substituted hydrazines


Дәйексөз келтіру

Толық мәтін

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Аннотация

Reaction direction of N-sulfonyl derivatives of 1,4-benzoquinone monoimine with substituted hydrazines depends on the redox potential of the quinone imine and on the basicity of the hydrazine. Aryl (alkyl)hydrazines of high basicity favor the reduction of quinone monoimine. In reactions with less basic aroylhydrazones N'-(4-oxocyclohexa-2,5-dienylidene)aroylhydrazides were obtained only from the alkylsubstituted in the quinoid ring N-sulfonyl derivatives possessing a lower redox potential.

Авторлар туралы

S. Konovalova

Donbass State Engineering Academy

Email: chimist@dgma.donetsk.ua
Украина, ul. Shkadinova 72, Kramatorsk, 84313

A. Avdeenko

Donbass State Engineering Academy

Хат алмасуға жауапты Автор.
Email: chimist@dgma.donetsk.ua
Украина, ul. Shkadinova 72, Kramatorsk, 84313

S. Goncharova

Sumy State University

Email: chimist@dgma.donetsk.ua
Украина, Sumy

V. D’yakonenko

Institute of Single Crystals

Email: chimist@dgma.donetsk.ua
Украина, Kharkiv

S. Shishkina

Institute of Single Crystals; Karazin Kharkiv National University

Email: chimist@dgma.donetsk.ua
Украина, Kharkiv; Kharkiv

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