Alkylation of 4,5-dihydro-1H-imidazole-2-thiol with iodomethylsilanes and -siloxanes
- Authors: Yarosh N.O.1, Zhilitskaya L.V.1, Shagun L.G.1, Dorofeev I.A.1, Larina L.I.1
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Affiliations:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Issue: Vol 53, No 7 (2017)
- Pages: 1066-1070
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/216576
- DOI: https://doi.org/10.1134/S107042801707017X
- ID: 216576
Cite item
Abstract
The alkylation of 4,5-dihydro-1H-imidazole-2-thiol with 1-iodomethyl(dimethyl)phenylsilane, 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane, and 1,3-bis(iodomethyl)-1,1,3,3-tetramethyldisiloxane involved iodine-catalyzed cleavage of the Si–Csp2 and Si–O bonds with liberated (in situ) hydrogen iodide to afford 2-({[(4,5-dihydro-1H-imidazolium-2-ylsulfanyl)methyl]-1,1,3,3-tetramethyldisiloxanylmethyl}sulfanyl)-4,5-dihydro-1H-imidazolium di- and tetraiodides. Replacement of iodide ion in the products by triiodide gives new organosilicon ionic liquids with several charged fragments.
About the authors
N. O. Yarosh
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
L. V. Zhilitskaya
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
L. G. Shagun
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
I. A. Dorofeev
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
L. I. Larina
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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