Alkylation of 4,5-dihydro-1H-imidazole-2-thiol with iodomethylsilanes and -siloxanes


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Abstract

The alkylation of 4,5-dihydro-1H-imidazole-2-thiol with 1-iodomethyl(dimethyl)phenylsilane, 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane, and 1,3-bis(iodomethyl)-1,1,3,3-tetramethyldisiloxane involved iodine-catalyzed cleavage of the Si–Csp2 and Si–O bonds with liberated (in situ) hydrogen iodide to afford 2-({[(4,5-dihydro-1H-imidazolium-2-ylsulfanyl)methyl]-1,1,3,3-tetramethyldisiloxanylmethyl}sulfanyl)-4,5-dihydro-1H-imidazolium di- and tetraiodides. Replacement of iodide ion in the products by triiodide gives new organosilicon ionic liquids with several charged fragments.

About the authors

N. O. Yarosh

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. V. Zhilitskaya

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. G. Shagun

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

I. A. Dorofeev

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. I. Larina

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

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