Lanthanide Double-Decker Complexes with Tetra- tert -butyltetrabenzoporphyrin and Phthalocyanine Ligands. Synthesis and Properties

A. I. Koptyaev; N. E. Galanin; G. P. Shaposhnikov

doi:10.1134/S1070428019070042

Lanthanide Double-Decker Complexes with Tetra-tert-butyltetrabenzoporphyrin and Phthalocyanine Ligands. Synthesis and Properties

作者: Koptyaev A.I.¹, Galanin N.E.¹, Shaposhnikov G.P.¹
隶属关系:
1. Ivanovo State University of Chemistry and Technology
期: 卷 55, 编号 7 (2019)
页面: 944-950
栏目: Article
URL: https://bakhtiniada.ru/1070-4280/article/view/220839
DOI: https://doi.org/10.1134/S1070428019070042
ID: 220839

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详细

Mixed-ligand double-decker lutetium, erbium, dysprosium, gadolinium, and europium complexes with tetra-tert-butyltetrabenzoporphyrin and phthalocyanine have been synthesized, and their structure was confirmed by IR, ¹H NMR, and mass spectra. Relations have been found between the electronic absorption and luminescence spectra of the complexes and radius of the central metal ion.