Email this article Chemical Transformations of Tetracyclo[3.3.1.13,7.01,3]decane (1,3-Dehydroadamantane): VII. Reaction of 1,3-Dehydroadamantane with Alkanediols and Amino Alcohols
- Authors: Butov G.M.1,2, Mokhov V.M.2
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Affiliations:
- Volzhsky Polytechnic Institute (Branch)
- Volgograd State Technical University
- Issue: Vol 54, No 12 (2018)
- Pages: 1760-1763
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/219488
- DOI: https://doi.org/10.1134/S1070428018120035
- ID: 219488
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Abstract
The reaction of 1,3-dehydroadamantane with C2–C6 α,ω-alkanediols selectively afforded ω-(adamantan- 1-yloxy)alkan-1-ols in 87–94% yield. The reaction of 1,3-dehydroadamantane with ω-aminoalkan-1- ols (2-aminoethanol and 3-aminopropan-1-ol) gave mixtures of addition products through the oxygen and nitrogen atoms, which can be readily separated by fractional vacuum distillation or crystallization.
About the authors
G. M. Butov
Volzhsky Polytechnic Institute (Branch); Volgograd State Technical University
Author for correspondence.
Email: butov@volpi.ru
Russian Federation, ul. Engel’sa 42a, Volzhsky, Volgograd oblast, 404121; pr. Lenina 28, Volgograd, 400131
V. M. Mokhov
Volgograd State Technical University
Email: butov@volpi.ru
Russian Federation, pr. Lenina 28, Volgograd, 400131
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