Regio- and Stereoselective Synthesis of (Z)-2-Chloro-2-phenyl-1-propylethenyltellanes


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Abstract

The regio- and stereoselective reaction of tellurium tetrachloride with 1-phenylpent-1-yne was used to develop efficient methods of synthesis of trichloro[(Z)-2-chloro-2-phenyl-1-propylethenyl]-λ4-tellane and 1,2 -bis[(Z)-2-chloro-2-phenyl-1-propylethenyl]ditellane in 95 and 80% yields, respectively.

About the authors

M. V. Musalova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: amosova@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. A. Ivanova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: amosova@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

M. V. Musalov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: amosova@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

V. A. Potapov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: amosova@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

S. V. Zinchenko

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: amosova@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

S. V. Amosova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: amosova@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

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