Отправить статью по E-mail Fused Imidazoles: II. Synthesis of Nitro Derivatives of 6,7-Dihydro-5H-pyrrolo[1,2-a]imidazoles
- Авторы: Kavina M.A.1,2, Sizov V.V.1, Yakovlev I.P.2
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Учреждения:
- KEM Scientific and Production Company
- St. Petersburg State Chemical and Pharmaceutical University
- Выпуск: Том 54, № 11 (2018)
- Страницы: 1689-1696
- Раздел: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/219407
- DOI: https://doi.org/10.1134/S1070428018110118
- ID: 219407
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Аннотация
Nitration of 6-substituted 2-chloro-6,7-dihydro-5H-pyrrolo[1,2-a]imidazoles was used to synthesize the corresponding 3-nitro derivatives. 6-Substituted 6,7-dihydro-5H-pyrrolo[1,2-a]imidazoles are highly selectively nitrated to the 2-position. 6-Substituted 2-amino-3-nitro-, 3-amino-2-nitro-, and 2-azido-3-nitro-6,7-dihydro- 5H-pyrrolo[1,2-a]imidazoles were synthesized. 2-Nitro-6,7-dihydro-5H-pyrrolo[1,2-a]imidazole was nitrated with a mixture of sulfuric and nitric acids to obtain 2,3-dinitro-6,7-dihydro-5H-pyrrolo[1,2-a]imidazole.
Об авторах
M. Kavina
KEM Scientific and Production Company; St. Petersburg State Chemical and Pharmaceutical University
Email: vvsizov@list.ru
Россия, ul. Zavodskaya 3, bld. 142, Kuzmolovskii, Leningrad oblast, 188663; ul. Professora Popova 14A, St. Petersburg, 197376
V. Sizov
KEM Scientific and Production Company
Автор, ответственный за переписку.
Email: vvsizov@list.ru
Россия, ul. Zavodskaya 3, bld. 142, Kuzmolovskii, Leningrad oblast, 188663
I. Yakovlev
St. Petersburg State Chemical and Pharmaceutical University
Email: vvsizov@list.ru
Россия, ul. Professora Popova 14A, St. Petersburg, 197376
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