Enviar artigo por via de e-mail Synthesis and Transformations of 2-(Adamantan-1-yl)aziridine
- Autores: Leonova M.V.1, Belaya N.V.1, Baimuratov M.R.1, Klimochkin Y.N.1
-
Afiliações:
- Samara State Technical University
- Edição: Volume 54, Nº 11 (2018)
- Páginas: 1643-1651
- Seção: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/219370
- DOI: https://doi.org/10.1134/S1070428018110040
- ID: 219370
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
Mono- and disubstituted aziridines derived from sterically hindered olefins of the adamantane series are synthesized. The opening of the aziridine ring under the action of acids is quite a regio- and stereoselective process. Depending on the nature of the nucleophilic agent, the opening of the 2,2-disubstituted aziridine ring can occur by the SN1 or SN2 mechanism.
Sobre autores
M. Leonova
Samara State Technical University
Autor responsável pela correspondência
Email: mvleon@mail.ru
Rússia, ul. Molodogvardeiskaya 244, Samara, 443100
N. Belaya
Samara State Technical University
Email: mvleon@mail.ru
Rússia, ul. Molodogvardeiskaya 244, Samara, 443100
M. Baimuratov
Samara State Technical University
Email: mvleon@mail.ru
Rússia, ul. Molodogvardeiskaya 244, Samara, 443100
Yu. Klimochkin
Samara State Technical University
Email: mvleon@mail.ru
Rússia, ul. Molodogvardeiskaya 244, Samara, 443100
Arquivos suplementares
