Halocyclization of products of allyl isothiocyanate addition to acyclic methylene active compounds

M. B. Litvinchuk; A. V. Bentya; N. Yu. Slyvka; M. V. Vovk

doi:10.1134/S1070428017050104

Halocyclization of products of allyl isothiocyanate addition to acyclic methylene active compounds

Authors: Litvinchuk M.B.¹, Bentya A.V.², Slyvka N.Y.¹, Vovk M.V.²
Affiliations:
1. Lesya Ukrainka Eastern-European National University
2. Institute of Organic Chemistry
Issue: Vol 53, No 5 (2017)
Pages: 709-716
Section: Article
URL: https://bakhtiniada.ru/1070-4280/article/view/216196
DOI: https://doi.org/10.1134/S1070428017050104
ID: 216196

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Abstract

Products of allyl isothiocyanate addition to methylene active compounds, salt-like N-allyl-N,S-ketenacetals or N-allylthioamides, react with iodine, bromine or N-bromosuccinimide with the formation of derivatives of 2-ylidene-5-halomethylthiazolidines. A dependence was found of isomeric composition of obtained thiazolidines on the solvent nature.