Email this article Reactions of aromatic compounds with xenon difluoride
- Authors: Bardin V.V.1,2, Adonin N.Y.2,3
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Affiliations:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk State University
- Boreskov Institute of Catalysis, Siberian Branch
- Issue: Vol 52, No 10 (2016)
- Pages: 1400-1407
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/215018
- DOI: https://doi.org/10.1134/S1070428016100055
- ID: 215018
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Abstract
Reactions of substituted benzenes C6H5R (R = Me, F, Cl, Br, CF3, NO2) with xenon difluoride in the presence of boron trifluoride–diethyl ether complex in weakly acidic (1,1,1,3,3-pentafluorobutane) and weakly basic media (acetonitrile) have been studied. These reactions lead to the formation of fluorobenzene derivatives FC6H4R (isomer mixture) together with isomeric difluorobenzenes and fluorinated and non-fluorinated biphenyls. The results have been compared with previously reported data obtained in other solvents using other catalysts.
About the authors
V. V. Bardin
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk State University
Email: adonin@catalysis.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
N. Yu. Adonin
Novosibirsk State University; Boreskov Institute of Catalysis, Siberian Branch
Author for correspondence.
Email: adonin@catalysis.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090; pr. Akad. Lavrent’eva 5, Novosibirsk, 630090
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