Synthesis and oxidation of sulfides based on caryophyllene oxide and phenylmethanethiol


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Abstract

Lewis acid-catalyzed reaction of (–)-caryophyllene oxide with phenylmethanethiol gave sulfides with clovane and caryophyllane structure which were oxidized to the corresponding sulfoxides and sulfones in 74 and 84% yield, respectively.

About the authors

Yu. V. Gyrdymova

Institute of Chemistry, Komi Science Center, Ural Branch

Author for correspondence.
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

E. S. Izmest’ev

Institute of Chemistry, Komi Science Center, Ural Branch

Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

S. A. Rubtsova

Institute of Chemistry, Komi Science Center, Ural Branch

Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

A. V. Kutchin

Institute of Chemistry, Komi Science Center, Ural Branch

Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

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