6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)-1,2- benzoquinone]: Synthesis and properties


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详细

Preparation method is developed for a new 6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)- 1,2-benzoquinone], including the stage of 3,5-di(tert-butyl)pyrocatechol aminoalkylation by Mannich reaction followed by oxidation. The molecular structure of one of its hydrolysis products, 4,6-di(tert-butyl)-2,3-dihydroxybenzaldehyde, is established by X-ray diffraction (XRD) analysis.

作者简介

Yu. Sayapin

Southern Scientific Center of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: sayapin@ipoc.rsu.ru
俄罗斯联邦, ul. Chekhova 41, Rostov-on-Don, 344006

I. Tupaeva

Institute of Physical and Organic Chemistry at Southern Federal University

Email: sayapin@ipoc.rsu.ru
俄罗斯联邦, Rostov-on-Don

V. Tkachev

Institute of Problems of Chemical Physics

Email: sayapin@ipoc.rsu.ru
俄罗斯联邦, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

G. Shilov

Institute of Problems of Chemical Physics

Email: sayapin@ipoc.rsu.ru
俄罗斯联邦, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

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