Email this article N-(4-methoxy-3-nitrobenzyl) derivatives of some nitrogen-containing heterocycles
- Authors: Harutyunyan A.A.1
-
Affiliations:
- Mndzhoyan Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
- Issue: Vol 52, No 1 (2016)
- Pages: 76-79
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/213512
- DOI: https://doi.org/10.1134/S1070428016010140
- ID: 213512
Cite item
Open Access
Access granted
Subscription Access
Abstract
A number of nitrogen heterocycles reacted with 4-methoxy-3-nitrobenzyl chloride in dimethyl-formamide in the presence of potassium carbonate to give the corresponding N-(4-methoxy-3-nitrobenzyl) derivatives. The reaction of 5-fluoro-1,3-bis(4-methoxy-3-nitrobenzyl)pyrimidine-2,4(1H,3H)-dione with aqueous methylamine afforded N,N′-bis(4-methylamino-3-nitrobenzyl)urea, whereas analogous reaction with 1-(4-methoxy-3-nitrobenzyl)-2-(methylsulfanyl)-1H-benzimidazole resulted in substitution of the methoxy group by methylamino.
Keywords
About the authors
A. A. Harutyunyan
Mndzhoyan Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Author for correspondence.
Email: harutyunyan.arthur@yahoo.com
Armenia, pr. Azatutyan 26, Yerevan, 0014
Supplementary files
