N-(4-methoxy-3-nitrobenzyl) derivatives of some nitrogen-containing heterocycles


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A number of nitrogen heterocycles reacted with 4-methoxy-3-nitrobenzyl chloride in dimethyl-formamide in the presence of potassium carbonate to give the corresponding N-(4-methoxy-3-nitrobenzyl) derivatives. The reaction of 5-fluoro-1,3-bis(4-methoxy-3-nitrobenzyl)pyrimidine-2,4(1H,3H)-dione with aqueous methylamine afforded N,N′-bis(4-methylamino-3-nitrobenzyl)urea, whereas analogous reaction with 1-(4-methoxy-3-nitrobenzyl)-2-(methylsulfanyl)-1H-benzimidazole resulted in substitution of the methoxy group by methylamino.

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A. Harutyunyan

Mndzhoyan Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry

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Email: harutyunyan.arthur@yahoo.com
亚美尼亚, pr. Azatutyan 26, Yerevan, 0014

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