Electrochemical oxidative phosphorylation of azoles in the presence of silver catalysts


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A new method for the phosphorylation of benzo-1,3-azoles (benzoxazole, benzothiazole, and 3-methylindole) with diethyl phosphite by electrocatalytic oxidation was proposed. The process occurs under electrochemical mild conditions (room temperature, normal pressure) in the presence of silver salts or silver oxide. This method allows one to obtain 2-phosphorylated products of benzo-1,3-azoles in good yield (up to 75%).

作者简介

E. Yurko

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

T. Gryaznova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

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Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

V. Khrizanforova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

M. Khrizanforov

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

A. Toropchina

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

Yu. Budnikova

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

O. Sinyashin

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences

Email: tatyanag@iopc.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088

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