Email this article Electrochemical oxidative phosphorylation of azoles in the presence of silver catalysts
- Authors: Yurko E.O.1, Gryaznova T.V.1, Khrizanforova V.V.1, Khrizanforov M.N.1, Toropchina A.V.1, Budnikova Y.H.1, Sinyashin O.G.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Issue: Vol 67, No 1 (2018)
- Pages: 102-107
- Section: Article
- URL: https://bakhtiniada.ru/1066-5285/article/view/241939
- DOI: https://doi.org/10.1007/s11172-018-2043-5
- ID: 241939
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Abstract
A new method for the phosphorylation of benzo-1,3-azoles (benzoxazole, benzothiazole, and 3-methylindole) with diethyl phosphite by electrocatalytic oxidation was proposed. The process occurs under electrochemical mild conditions (room temperature, normal pressure) in the presence of silver salts or silver oxide. This method allows one to obtain 2-phosphorylated products of benzo-1,3-azoles in good yield (up to 75%).
About the authors
E. O. Yurko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
T. V. Gryaznova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Author for correspondence.
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
V. V. Khrizanforova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
M. N. Khrizanforov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
A. V. Toropchina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
Yu. H. Budnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
O. G. Sinyashin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
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