Electrochemical oxidative phosphorylation of azoles in the presence of silver catalysts
- Autores: Yurko E.O.1, Gryaznova T.V.1, Khrizanforova V.V.1, Khrizanforov M.N.1, Toropchina A.V.1, Budnikova Y.H.1, Sinyashin O.G.1
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Afiliações:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Edição: Volume 67, Nº 1 (2018)
- Páginas: 102-107
- Seção: Article
- URL: https://bakhtiniada.ru/1066-5285/article/view/241939
- DOI: https://doi.org/10.1007/s11172-018-2043-5
- ID: 241939
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Resumo
A new method for the phosphorylation of benzo-1,3-azoles (benzoxazole, benzothiazole, and 3-methylindole) with diethyl phosphite by electrocatalytic oxidation was proposed. The process occurs under electrochemical mild conditions (room temperature, normal pressure) in the presence of silver salts or silver oxide. This method allows one to obtain 2-phosphorylated products of benzo-1,3-azoles in good yield (up to 75%).
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Sobre autores
E. Yurko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
T. Gryaznova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
V. Khrizanforova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
M. Khrizanforov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
A. Toropchina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
Yu. Budnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
O. Sinyashin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: tatyanag@iopc.ru
Rússia, 8 ul. Arbuzova, Kazan, 420088
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