Отправить статью по E-mail Temperature-Phase Dependence of the Vibration Spectrum and Orientation Mobility of the Tetrafluoroborate Ion in n-Bu4NBF4 Organic Salt
- Авторы: Rabadanov K.S.1, Gafurov M.M.1, Uvarov N.F.2, Ulikhin A.S.2
-
Учреждения:
- Dagestan Scientific Centre of the Russian Academy of Sciences, Federal Multiple-Access Centre “Analytical Spectroscopy”
- Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences
- Выпуск: Том 60, № 12 (2018)
- Страницы: 2593-2597
- Раздел: Phase Transitions
- URL: https://bakhtiniada.ru/1063-7834/article/view/204608
- DOI: https://doi.org/10.1134/S1063783418120235
- ID: 204608
Цитировать
Открытый доступ
Доступ предоставлен
Только для подписчиков
Аннотация
The structural and dynamic properties of a tetrafluoroborate ion in n-Bu4NBF4 organic salt at different temperatures and phase states were studied by oscillation spectroscopy methods. The results of calculations of the energy and relaxation parameters have shown that in the plastic phase, a \({\text{BF}}_{4}^{ - }\) ion is characterized by a low reorientation energy as compared with that of the crystalline phase.
Об авторах
K. Rabadanov
Dagestan Scientific Centre of the Russian Academy of Sciences,Federal Multiple-Access Centre “Analytical Spectroscopy”
Автор, ответственный за переписку.
Email: rksh83@mail.ru
Россия, Makhachkala
M. Gafurov
Dagestan Scientific Centre of the Russian Academy of Sciences,Federal Multiple-Access Centre “Analytical Spectroscopy”
Email: rksh83@mail.ru
Россия, Makhachkala
N. Uvarov
Institute of Solid State Chemistry and Mechanochemistry,Siberian Branch, Russian Academy of Sciences
Email: rksh83@mail.ru
Россия, Novosibirsk
A. Ulikhin
Institute of Solid State Chemistry and Mechanochemistry,Siberian Branch, Russian Academy of Sciences
Email: rksh83@mail.ru
Россия, Novosibirsk
Дополнительные файлы
