The Influence of Relative Content of a Metal Component in a Dielectric Matrix on the Formation and Dimensions of Cobalt Nanocrystallites in Cox(MgF2)100 – x Film Composites

Resumo

The influence of relative content of a metal component on the phase composition and substructure of Co_x(MgF₂)_100 – x in a wide range of x = 16–63 at % is studied by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared (IR) spectroscopy. The layers of nanocomposite with a micron thickness have been obtained by the ion-beam sputtering of the target in the argon environment. The results reveal that the relative metal cobalt content in the MgF₂ dielectric matrix strongly affects the phase composition and substructure of nanocomposites. With a lower content of cobalt, it is in the amorphous state in the form of clusters in the MgF₂ nanocrystalline matrix. An increase of cobalt content to x = 29 at % on a sitall substrate and to x = 42 at % on a glass substrate in the X-ray amorphous MgF₂ dielectric matrix leads to the formation of cobalt nanocrystals with a hexagonal crystallographic system, whose sizes are on the order of 10 nm. These are predominately oriented in the basis plane of the (001) hexagonal lattice of α-Со. A further increase of cobalt content to c = 59 at % enlarges the α-Со nanocrystals to ~20 nm with retaining the same orientation. In accordance with a fine structure analysis of XPS spectra of Со 2p and О 1s, cobalt is strongly oxidized on the surface of all the composites; only on the surface of samples with a low content of Co is X‑ray amorphous cobalt found in a metallic state along with cobalt oxide. The IR spectra of these samples with the lowest metal phase content exhibit the pronounced modes from the nanocrystalline MgF₂ dielectric phase.