High-temperature specific heat of Bi2GeO5 and SmBiGeO5 compounds


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Abstract

The SmBiGeO5 compound is synthesized from Sm2O3, Bi2O3, and GeO2 by solid-state synthesis with subsequent annealing at 1003, 1073, 1123, 1143, 1173, and 1223 K. The metastable Bi2GeO5 compound is prepared from melt. Temperature dependences of specific heat of Bi2GeO5 (350–1000 K) and SmBiGeO5 (370–1000 K) are measured by differential scanning calorimetry. Basing on the experimental dependences CP = f(T), the thermodynamic functions of the oxide compounds are calculated.

About the authors

L. T. Denisova

Institute of Non-Ferrous Metals and Material Science

Author for correspondence.
Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

N. V. Belousova

Institute of Non-Ferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

N. A. Galiakhmetova

Institute of Non-Ferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

V. M. Denisov

Institute of Non-Ferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

V. P. Zhereb

Institute of Non-Ferrous Metals and Material Science

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

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