Antiferroelectric films of deuterated betaine phosphate

Resumo

Thin films of partially deuterated betaine phosphate have been grown by the evaporation on Al₂O₃(110) and NdGaO₃(001) substrates with a preliminarily deposited structure of interdigitated electrodes. The grown films have a polycrystalline block structure with characteristic dimensions of blocks of the order of 0.1–1.5 mm. The degree of deuteration of the films D varies in the range of 20–50%. It has been found that, at the antiferroelectric phase transition temperature T_c^afe = 100–114 K, the fabricated structures exhibit an anomaly of the electrical capacitance C, which is not accompanied by a change in the dielectric loss tangent tanδ. The strong-signal dielectric response is characterized by the appearance of a ferroelectric nonlinearity at temperatures T >T_c^afe, which is transformed into an antiferroelectric nonlinearity at T <T_c^afe. With a further decrease in the temperature, double dielectric hysteresis loops appear in the antiferroelectric phase. The dielectric properties of the films have been described within the framework of the Landau-type thermodynamic model taking into account the biquadratic coupling ξP²η² between the polar order parameter P and the nonpolar order parameter η with a positive coefficient ξ. The E–T phase diagram has been constructed.