Binary extraction of lanthanides (III) nitrates with carboxylates and dialkylphosphates of secondary and tertiary amines
- 作者: Kalyakin S.N.1, Kuzmin V.I.1, Mulagaleeva M.A.1
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隶属关系:
- Institute of Chemistry and Chemical Technology, Siberian Branch
- 期: 卷 50, 编号 5 (2016)
- 页面: 878-883
- 栏目: Chemistry and Technology of Rare, Trace, and Radioactive Elements
- URL: https://bakhtiniada.ru/0040-5795/article/view/171165
- DOI: https://doi.org/10.1134/S0040579516050080
- ID: 171165
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详细
The separation of lanthanide (III) ions with binary extractants based on carboxylates, di-(2-ethylhexyl) phosphates of secondary and tertiary amines and their mixtures has been studied. The parameters of lanthanide nitrates extraction from the aqueous phase by solutions of these substances in nonpolar diluents have been found to fit the binary extraction mechanism. For systems containing di-(2-ethylhexyl) phosphate and caprate of dioctylammonium and trioctylammonium, synergistic effects have been observed.
作者简介
S. Kalyakin
Institute of Chemistry and Chemical Technology, Siberian Branch
Email: maral7508@mail.ru
俄罗斯联邦, Krasnoyarsk, 660049
V. Kuzmin
Institute of Chemistry and Chemical Technology, Siberian Branch
Email: maral7508@mail.ru
俄罗斯联邦, Krasnoyarsk, 660049
M. Mulagaleeva
Institute of Chemistry and Chemical Technology, Siberian Branch
编辑信件的主要联系方式.
Email: maral7508@mail.ru
俄罗斯联邦, Krasnoyarsk, 660049
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