Effect of adding ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate on the coordination environment of Li+ ions in propylene carbonate, according to data from IR spectroscopy and quantum chemical modeling


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The effect ionic liquid (IL) 1-ethyl-3-methylimidazolium tetrafluoroborate has on the coordination environment of Li+ cations in carbonate solvents is studied by means of IR spectroscopy and quantum chemical modeling using the example of propylene carbonate (PC). LiBF4 is used as the lithium salt. This system is promising for use as an electrolyte in lithium power sources (LPSs), but the mechanism of ionic conductivity by Li+ ions in such systems has yet to be studied in full.

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A. Shestakov

Institute of Problems of Chemical Physics

编辑信件的主要联系方式.
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

A. Yudina

Institute of Problems of Chemical Physics

Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

G. Tulibaeva

Institute of Problems of Chemical Physics

Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

Yu. Shul’ga

Institute of Problems of Chemical Physics

Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

A. Ignatova

Institute of Problems of Chemical Physics

Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

O. Yarmolenko

Institute of Problems of Chemical Physics

Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

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