Effect of adding ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate on the coordination environment of Li+ ions in propylene carbonate, according to data from IR spectroscopy and quantum chemical modeling
- 作者: Shestakov A.F.1, Yudina A.V.1, Tulibaeva G.Z.1, Shul’ga Y.M.1, Ignatova A.A.1, Yarmolenko O.V.1
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隶属关系:
- Institute of Problems of Chemical Physics
- 期: 卷 91, 编号 8 (2017)
- 页面: 1444-1450
- 栏目: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/169657
- DOI: https://doi.org/10.1134/S0036024417080301
- ID: 169657
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详细
The effect ionic liquid (IL) 1-ethyl-3-methylimidazolium tetrafluoroborate has on the coordination environment of Li+ cations in carbonate solvents is studied by means of IR spectroscopy and quantum chemical modeling using the example of propylene carbonate (PC). LiBF4 is used as the lithium salt. This system is promising for use as an electrolyte in lithium power sources (LPSs), but the mechanism of ionic conductivity by Li+ ions in such systems has yet to be studied in full.
作者简介
A. Shestakov
Institute of Problems of Chemical Physics
编辑信件的主要联系方式.
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
A. Yudina
Institute of Problems of Chemical Physics
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
G. Tulibaeva
Institute of Problems of Chemical Physics
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
Yu. Shul’ga
Institute of Problems of Chemical Physics
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
A. Ignatova
Institute of Problems of Chemical Physics
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
O. Yarmolenko
Institute of Problems of Chemical Physics
Email: oyarm@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
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