Can enantiomers be separated in achiral chromatographic systems?
- 作者: Davankov V.A.1
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隶属关系:
- Nesmeyanov Institute of Organoelement Compounds
- 期: 卷 90, 编号 10 (2016)
- 页面: 2119-2121
- 栏目: Discussions
- URL: https://bakhtiniada.ru/0036-0244/article/view/168909
- DOI: https://doi.org/10.1134/S0036024416100083
- ID: 168909
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详细
Consideration of chromatography of a nonracemic mixture on an achiral sorbent from a stereochemical point of view allows the claim that partial separation of the excess enantiomer zone from the racemate zone is possible only with analytes capable of self-associating under the conditions of the chromatographic column. It is from these positions that features of this process can be explained and conditions for its maximal proceeding formulated.
作者简介
V. Davankov
Nesmeyanov Institute of Organoelement Compounds
编辑信件的主要联系方式.
Email: davank@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
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