Thermodynamic properties and amorphization of Zr–Si melts


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The relationship between the thermodynamic properties of Zr–Si liquid alloys and their propensity to amorphization is studied. The temperature–concentration dependences of the thermodynamic properties of melts are presented using the concept of associated solutions. It is shown that the range of amorphization coincides with the range of the predominant concentration of Zr3Si associative groups with low formation entropy.

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N. Arutyunyan

Department of Chemistry

编辑信件的主要联系方式.
Email: naarutyunyan@rambler.ru
俄罗斯联邦, Moscow, 119991

A. Zaitsev

Department of Chemistry; Bardin Central Research Institute of Ferrous Metals

Email: naarutyunyan@rambler.ru
俄罗斯联邦, Moscow, 119991; Moscow, 105005

S. Dunaev

Department of Chemistry

Email: naarutyunyan@rambler.ru
俄罗斯联邦, Moscow, 119991

N. Shaposhnikov

Department of Chemistry

Email: naarutyunyan@rambler.ru
俄罗斯联邦, Moscow, 119991

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